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I agree, it may be time for you to remind him in front of your daughter that he still owes you for child support, and that paying for college would be a good way to start to even up the score.
Its pretty common in children with divorced or seperated parents (especially if there sheltered from what really happened or one parent talks crap about the other) most of this will most likely blow over as she grows up but you may need to calmly sit her down and explain the situation to her. Im sure she loves you with all her heart she's just confused and hurt
You'll be in my prayers -theflying400
She'll be more years an adult than an adolescent. She will understand more years than she doesn't. Rejoice when she spends time with her father, and be glad for her: this will take the heat out of things for her and when you say 'what about me' it will be better understood.
Book her in sooner than he does so that you get the best dates. Make events. Look around for opportunities. I am taking the kids ice skating this weekend. If they have an activity they are more likely to come. :)