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Sincerely,
eagleandfrog
You could call and congratulate her, if you truly are happy for her and it sounds like you are. You might not want to bring up the topic of your brothers belongings in the same phone call. Have you ever thought of writing her a brief letter asking that she give you all the clothing/personal items that I'm sure she won't want in the house (I'm assuming she and the new hubby will live in the same house she shared with your brother).
People can always misconstrue your intentions in a phone call--but it seems to me that they respect the fact that someone took the time to sit down and write them a letter. I bet it might work. It could be the final gesture of her leaving the old life behind and starting anew. Maybe you could work something like that into your letter.
As far as after the wedding, it will be up to her how much contact she will want. My hunch is she will want to close the door on everything from her old life. If I were you, I'd send her cards for her birthday, etc., and call her only now and then to see how things are going.
It's too bad that she doesn't want your family over to her house. There are so many people in the world who are alone. It's hard to imagine cutting off people who care and want to be a part of her life.